Gold dimer in neon: an absorption and fluorescence study
نویسندگان
چکیده
We report for the first time the absorption and fluorescence spectra of gold dimers in a neon matrix. The dimer absorption spectra show the A←X transition predicted from measurements in the gas phase and not observed so far in a matrix, as well as the so-called B←X and C←X transitions. Fluorescence measurements on the atom reveal new emission lines at 1.97, 3.59 and 4.09 eV that can be assigned to the P1/2 → D3/2, P1/2 → D5/2 and the P3/2 → D5/2 transitions. For the dimer, excitation of both A and B state results in distinct emission spectra with vibrational structure. PACS. 36.40.Vz Optical properties of clusters
منابع مشابه
TWO PHOTON TRANSITIONS IN THE OPTOGALVANIC SPECTRUM OF NEON
Seventeen two-photon transitions for neon have been observed in the 580- 635 nm spectral region for use in the spectroscopic study of its higher excited levels, which are not accessible by one-photon absorption. To compare the two and one-photon absorption signals originating from the same lower level, an effort was made to record single-photon optogalvanic spectrum in the available wavele...
متن کاملThe Effect of Hydrophobicity and Hydrophilicity of Gold Nanoparticle on Proteins Structure and Function
The surface parameter of nanoparticles such as hydrophobicity and a hydrophilicity on protein structure and function is very important. In this study, conformational changes of glucose oxidase (GOx) in the mercaptopurine: GNPs and 11-mercaptoundecanoic acid: GNPs as a hydrophobic and a hydrophilic GNPs surface was investigated by various spectroscopic techniques, including: UV-Vis absorption, f...
متن کاملThe Effect of Hydrophobicity and Hydrophilicity of Gold Nanoparticle on Proteins Structure and Function
The surface parameter of nanoparticles such as hydrophobicity and a hydrophilicity on protein structure and function is very important. In this study, conformational changes of glucose oxidase (GOx) in the mercaptopurine: GNPs and 11-mercaptoundecanoic acid: GNPs as a hydrophobic and a hydrophilic GNPs surface was investigated by various spectroscopic techniques, including: UV-Vis absorption, f...
متن کاملOptical absorption of small copper clusters in neon: Cu(n), (n = 1-9).
We present optical absorption spectra in the UV-visible range (1.6 eV < ℏω < 5.5 eV) of mass selected neutral copper clusters Cu(n)(n = 1-9) embedded in a solid neon matrix at 7 K. The atom and the dimer have already been measured in neon matrices, while the absorption spectra for sizes between Cu(3) and Cu(9) are entirely (n = 6-9) or in great part new. They show a higher complexity and a larg...
متن کاملEXPERIMENTAL INVESTIGATION OF THE POPULATION DENSITIES OF LOWEREXCITED STATES OF NEON
Many studies employing various methods have been carried out into the number densities of excited atoms in electrical discharges with inert gases [1,2,3], but the ranges of the discharge current and gas pressure is very limited in them all. In this work, the population densities of 3S, 3s' of neon have been investigated using the atomic absorption method. Since the discharge current and gas...
متن کامل